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Guide to Selecting Precipitated Silica in Coatings: Achieving the Perfect Match of Performance and Application

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In coating formulation design, the selection of precipitated silica directly impacts product performance and application results. As a functional filler, precise selection is a crucial challenge for coating engineers.


Key Selection Parameters: First, consider the specific surface area of the precipitated silica.  Precipitated silica with a specific surface area of 200-300 m²/g is generally suitable for most architectural coatings, providing good thixotropy and anti-settling properties; while high-end industrial coatings should use fumed silica (specific surface area ≥ 200 m²/g) to ensure excellent transparency and mechanical strength. Particle size distribution is also important; products with a D50 in the range of 5-15 μm are easiest to disperse and offer excellent stability.

 

System Compatibility Principles: Water-based coatings should use hydrophilic precipitated silica treated with silane coupling agents, with a pH value controlled between 6.5 and 8.0; while solvent-based systems require hydrophobically modified products with a contact angle > 120°. For high-gloss clear coats, prioritize low-structure, high-purity precipitated silica; matte coatings require high-porosity products.

 

The Art of Performance Balancing: High specific surface area precipitated silica enhances thixotropy but may affect leveling. It is recommended to conduct stepwise addition tests (0.5%-3.0%) to find the optimal balance between anti-settling, application properties, and gloss. Also, pay attention to ignition loss (<5%) and sieve residue (<0.05%) to ensure batch consistency.

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