Reinforcement Mechanism and Performance Optimization of Silica in the Rubber Industry
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I. Basic Properties of Silica
Silica (silicon dioxide) is an important inorganic non-metallic material widely used as a reinforcing filler in the rubber industry. Its basic properties include:
Physical properties: Appearance is white powder or granules, true density is approximately 2.0 g/ml, apparent density is approximately 0.2 g/ml (for ordinary products), high temperature resistance, non-combustible, and good electrical insulation.
Chemical properties: Reacts with caustic soda and hydrofluoric acid, SiO2 content (dry basis) ≥ 90%, pH value 5.0-8.0, specific surface area between 145-300 m2/g depending on the application.
Main performance indicators: Tensile strength ≥ 17.0 MPa, 500% modulus ≥ 6.3 MPa, elongation at break ≥ 675%.
II. Reinforcement Mechanism of Silica on Rubber
The reinforcing effect of silica on rubber is mainly achieved through the following mechanisms:
Nanoparticle filling and interfacial bonding: Nanoscale silica (particle size 10-40 nm) can effectively fill the gaps between rubber molecular chains, forming a three-dimensional network structure to strengthen the rubber matrix.
Hydrogen bonding between surface silanol groups and rubber molecular chains: The silanol groups (-OH) on the surface of silica can form hydrogen bonds with rubber molecular chains, optimizing the stress transfer efficiency at the filler-matrix interface.
Structural effect: The aggregation of silica... The aggregates form a three-dimensional network structure in the rubber, restricting the thermal motion of the rubber molecular chains and thus improving the mechanical properties of the rubber.
Physical adsorption and chemical bonding: Rubber molecules are adsorbed onto the surface of silica through van der Waals forces (physical adsorption), while the active groups on the surface of silica can chemically react with rubber molecules to form chemical bonds (chemical bonding).
III. Methods for Optimizing the Performance of Silica in the Rubber Industry
The application performance of silica in rubber can be optimized through the following methods:
Addition amount control: The usual addition amount is 5%-50% of the rubber weight, adjusted specifically according to product performance requirements.
Use in combination with silane coupling agents: This can improve the interfacial bonding between silica and rubber, enhancing the reinforcing effect.
Nanoscale dispersion technology: Ensures that silica particles are uniformly dispersed in the rubber matrix, avoiding agglomeration.
Formulation optimization:
Used in combination with solution-polymerized styrene-butadiene rubber (SSBR)
Adding active agents such as diethylene glycol and glycerol to reduce the adsorption of accelerators by silica
Process control: Appropriately extending the mixing time to ensure uniform dispersion of high-structure silica.
IV. Application Cases and Performance Improvement Effects
1. Tire Industry Applications
Maxxis VICTRA SPORT 6 (VS6): Uses a "high-dispersion silica + rice husk material" formula, reducing rolling resistance by 12%, shortening wet braking distance by 9%, and increasing wear mileage by 10%.
Sailun EP3 Zero Pressure Safety Tire: Silica content reaches 70 phr, reducing rolling resistance by 38.4% and improving wet braking performance by 45.5%.
2. Shoe Sole Rubber Applications
Can completely replace carbon black in transparent and translucent shoe sole compounds.
Improves the wear resistance, hardness, tensile strength, and tear strength of shoe soles.
Service life is 2-3 times longer than ordinary rubber soles.
3. Other Rubber Products
Industrial seals: Enhanced strength and wear resistance.
Rubber tubes, rubber sheets, and other products: Improved heat resistance and impact resistance.
V. Future Development Trends
Environmentally friendly silica development: Using biomass raw materials such as rice husks to prepare silica, reducing environmental pollution.
Nanotechnology applications: Developing silica products with smaller particle sizes (below 10 nm) to improve reinforcement effects.
Multifunctional composite materials: Combining silica with other nanomaterials to give rubber more functionality.
Intelligent formula design: Using AI technology to optimize silica rubber formulations for precise performance control.
Through continuous technological innovation, the application of silica in the rubber industry will become more widespread, providing strong support for the performance improvement and industrial upgrading of rubber products.