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The mechanism of the effect of Silica ink performance

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The mechanism of the effect of Silica ink performance is mainly reflected in its high specific surface area, porous structure, optical properties and chemical stability. It optimizes the rheological, optical, covering and weather resistance of ink through various physical and chemical effects. The following is a specific analysis:

 

1. Rheological performance regulation mechanism

Silicaforms a three-dimensional network structure in the ink through its nano-scale particle size and high specific surface area (up to 380m²/g). This structure interacts with the ink matrix through hydrogen bonds or van der Waals forces, significantly improving the viscosity of the system and giving it thixotropic properties: under the action of shear force (such as during printing), the network structure is destroyed and the fluidity of the ink is enhanced; after the shear force disappears, the structure quickly recovers to prevent the ink from diffusing or sagging on the paper. This mechanism ensures stable transmission and precise positioning of the ink during high-speed printing.

 

2. Optical performance enhancement mechanism

The light scattering properties of Silicaare derived from the multiple reflections and refractions of light by its surface microstructure. Its porous structure can increase the optical path difference, increase the whiteness value of the ink by 10%-15%, and reduce the haze to less than 5%, significantly improving the clarity of the image. In the UV-visible light range, Silicaabsorbs harmful ultraviolet light (wavelength 200-400nm), reduces the degradation of organic dyes in the ink, improves the light fastness of the printed product by 1-2 levels, and extends the outdoor application life.

 

3. Mechanism of improving coverage performance

The micron-sized particles of Silica(particle size 5-50μm) form a dense accumulation layer in the ink, and its porosity can absorb 15%-20% of the solvent in the ink and reduce permeability. This feature allows the ink to form a uniform ink film of 0.5-1μm on the surface of the paper, and the hiding power (ISO 2471 standard) is increased by 20%-30%, reducing the phenomenon of bottom color print-through. In gravure printing, Silicacan fill the dot depressions, increase the solid density (Dmax) by 0.1-0.2, and enhance the expression of dark details.

 

4. Weathering performance enhancement mechanism

The Si-O-Si skeleton structure of silica gives it excellent chemical inertness. Under high temperature (80℃) and high humidity (RH 85%) environment, its mass loss rate is less than 0.5%/year. As a UV absorber, silica can inhibit the breakage of polymer chains in ink and reduce the yellowing index (Δb*) to below 3. In outdoor advertising inks, the color difference ΔE<2 of the sample with silica added after QUV accelerated aging for 300h, which is much lower than ΔE>5 of the sample without silica.

 

5. Printing adaptability optimization mechanism

Silica improves the wettability of non-absorbent substrates (such as PET, PP) by adjusting the surface tension of the ink (reduced to 25-30mN/m), and reduces the contact angle to below 30°. In inkjet printing, its anti-sedimentation effect makes the storage stability of the ink (50℃/14d) reach more than 98%, reducing the risk of nozzle clogging. At the same time, Silicacan reduce the viscoelasticity of ink, and improve the abrasion resistance of printed products (Taber 500g load) to 1,000 times without bottom exposure, meeting the friction resistance requirements of packaging printing.

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